
UF Chemical Engineering > People > Faculty > Dinesh O.
Shah |
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Dinesh O. Shah
Ph.D., 1965, Columbia University (1970)
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| Professor Emeritus |
Ph : 352-392-0877
shah@che.ufl.edu
425 Chemical Engineering Building |
| Faculty
Web Page |
| Areas |
| Interfacial phenomena in engineering and
biomedical systems |
| Molecular association in micelles, liquid
crystals and microemulsions |
| Nanoparticles for superconductors and magnetic
materials |
| Enzymic reactions at interfaces |
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Our research projects are in three major areas: biomedical,
surfactant solutions and advanced materials. In the biomedical
area, we investigate surface chemical aspects of polymer
adsorption on contact lenses in relation to biolubrication
and comfort in the eyes. We also study transdermal diffusion
of local anesthestics. 
In various engineering processes such as cleaning, lubrication
or dispersions, the adsorption of surfactants at the interface
is very important. The molecular aggregates of surfactants
are commonly known as micelles. We have shown that the
lifetime of micelles is related to their stability. The
more stable micelles lead to decreased flux when a new
surface is created. Thus, we have shown that the micelle
stability significantly influences the foaming, droplet
size in emulsions, wetting of textile fibers, and the
rate of solubilization of oil in detergent solutions.
Nanoparticles of superconductors and magnetic materials
can be produced using microemulsion processing. Here,
the micro droplets of water can be used as microreactors.
Two identical microemulsions containing different reactants
are mixed together so as to produce nanoparticles upon
collision and coalescence of micro droplets. The precipitation
reaction leads to the formation of nanoparticles in these
microreactors. We have further shown that such nanopowders
when used as the raw material can produce high density
superconductors which exhibit superior levitation due
to greater Meissner effect. The magnetic flux does not
go through such dense superconductors. We have further
shown using electron microscopy that the grain-size is
considerably larger in the nanoparticle derived samples
as compared to the conventionally prepared samples. The
research of our group has been supported by the National
Science Foundation and Electric Power Research Institute
as well as by several industrial companies (Alcon Laboratories,
Alcoa, Kimberly-Clark, Kraft, Procter & Gamble Company).
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| Major Equipment |
- Brookhaven quasielastic light scattering spectrometer
- Langmuir film balance
- Contact angle goniometer
- Perkin-Elmer fluorescence spectrophotometer
- Pressure-jump, temperature-jump and stopped-flow instruments
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| Recent Publications |
| 1. |
James-Smith, M.A., Shekhawat, D., Cheung,
S., Moudgil, B.M. and Shah, D.O., “ Effect of Chain
Length on Binding of Fatty Acids to Pluronics in Microemulsions,”
Colloids and Surfaces B-Biointerfaces, 62(1) (2008)
5. |
| 2. |
James-Smith, M.A., Shekhawat, D., Cheung,
S., Moudgil, B.M. and Shah, D.O., “ Role of Ethylene
Oxide and Propylene Oxide Groups of Pluronics in Binding
of Fatty Acid to Pluronics in Microemulsions,”
Journal of Surfactants and Detergents, 11(3) (2008)
237. |
| 3 |
James-Smith, M.A., Shekhawat, D. and
Shah, D.O., “ Importance of Micellar Lifetime and
Sub-Micellar Aggregates in Detergency Processes,”
Tenside Surfactants Detergents, 44(3) (2007) 142. |
| 4. |
Morey, T.E., Modell, J.H., Shekhawat,
D., Grand, T., Shah, D.O., Gravenstein, N., McGorray,
S.P. and Dennis, D.M., “ Preparation and Anesthetic
Properties of Propofol Microemulsions in Rats,”
Anesthesiology, 104(6) (2006) 1184. |
| 5. |
Paruchuri, V.K., Nalaskowski, J., Shah,
D.O. and Miller, J.D., “ The Effects of Cosurfactants
on Sodium Dodecyl Sulfate Micellar Structures at a Graphite
Surface,” Colloids and Surface A: Physiochem.
Eng. Aspects, 2722 (2006) 157. |
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